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Physicochemical Properties of Industrial Cellulose Diacetate Flakes
Date:December 10 , 2025Views:0

The following summarizes the typical physicochemical properties of industrial cellulose diacetate flakes (Cellulose Diacetate Flakes / CDA Flakes). The data is compiled based on common technical specifications from major industry suppliers (such as Eastman, Celanese, Daicel, and Cerdia). It applies to spinning grade, plastic grade, and general industrial processing applications.

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1. Basic Chemical Properties

Item

Typical Range

Description

Chemical Name

Cellulose Diacetate

Produced by partial esterification of natural cellulose

Degree of Substitution (DS)

2.2–2.5

Theoretical maximum DS = 3; diacetate indicates partial substitution of hydroxyl groups by acetyl groups

Acetyl Content

29–34 wt%

Higher DS corresponds to higher acetyl content

Purity / Main Component Content

≥ 99% (dry basis)

Industrial grade typically ≥ 99%

pH (10% ethanol solution)

5.0–7.0

Generally neutral to slightly acidic

Ash Content

≤ 0.05%

Industrial grade commonly ≤ 0.1%

2. Physical Properties

Item

Typical Value or Range

Description

Appearance

Transparent to milky-white flakes

Sheet/flake form, free of visible impurities

Density

1.28–1.30 g/cm³

At room temperature

Glass Transition Temperature (Tg)

≈ 185–200°C

CDA exhibits relatively high rigidity

Melting / Softening Point

~230–260°C (decomposition begins)

No true melting point; decomposes upon heating

Moisture Content

2.0–6.0%

Varies with storage conditions

Flake Size

3–20 mm

Depends on manufacturer processing

3. Solubility & Solvent Behavior

Solvent Type

Solubility

Acetone

Easily soluble (most commonly used)

Methylethyl ketone (MEK)

Good solubility

Ethyl acetate / ethanol mixtures

Soluble or partially soluble

Ethanol (pure)

Generally insoluble

Water

Insoluble, low hygroscopicity

Chloroform, dichloromethane

Soluble or swells

Acetone is the most widely used industrial solvent for cellulose diacetate, especially in tow-to-filter-rod processing and film formation.

4. Thermal Properties

Item

Typical Data

Thermal Decomposition Temperature

> 230°C

Weight Loss Range

230–350°C

Thermal Stability

Moderate; requires stabilizers or strict processing temperature control

5. Mechanical Properties (after curing/forming)

(The flakes themselves do not exhibit mechanical strength; the following reflects typical properties of shaped CDA materials for reference.)

Item

Value Range

Tensile Strength

40–60 MPa

Elongation at Break

10–20%

Flexural Modulus

1.5–2.5 GPa

6. Environmental & Safety Characteristics

High bio-based content (derived from natural cellulose)

Better biodegradability than many petrochemical plastics, though strongly affected by environmental conditions

Combustion products are relatively clean: primarily CO₂, H₂O, and acetic acid vapor

Good storage stability; requires moisture and heat protection

Non-toxic, low irritation, meets FDA/EFSA requirements for many applications

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